Crystal structure of [tris(pyridin-2-ylmethyl)amine-κ4 N]copper(II) bromide
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چکیده
In the asymmetric unit of the title compound, [CuBr(C18H18N4)]Br, there are three crystallographically independent cations. One of the cations exhibits positional disorder of the pyridin-2-yl-methyl groups over two sets of sites with refined occupancies of 0.672 (8) and 0.328 (8). The outer-sphere bromine counter-ion is severely disordered over multiple sites. In each cation, the Cu(II) ion is coordinated by the four N atoms of the tris-(pyridin-2-ylmeth-yl)amine ligand and one bromine and adopts a slightly distorted trigonal-bipyramidal geometry.
منابع مشابه
[(4-Methylbenzyl)bis(pyridin-2-ylmethyl)amine-κ3 N,N′,N′′]bis(thiocyanato-κS)copper(II) dichloromethane hemisolvate
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